pH meter calibration

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Main content

  1. The concept of pH
  2. pH meter
  3. Structure and operating principle
  4. Application
  5. Why should you calibrate a pH meter 
  6. Calibration procedure for pH meter

pH meters play a very important role in many fields, especially in agriculture and the environment. Controlling pH helps us make appropriate adjustments to production and environmental conditions, thereby optimizing the production process, growth and development of plants and animals.

1. The concept of pH
pH is an index measuring the activity of hydrogen ions (H+) in a solution, or simply a measure of the acidity or alkalinity of a solution. The pH scale ranges from 0 to 14, divided into 3 scales as follows:

  • Acidic solutions (pH less than 7): They have a high concentration of hydrogen ions (H +). The lower the pH, the more acidic the solution. For example, lemon juice and vinegar are acidic and have a pH of around 2-3.
  • Neutral solution (pH of 7): This solution has an equal concentration of hydrogen ions (H+) and hydroxide ions (OH-). Pure water is a neutral substance and has a pH of 7.
  • Alkaline or basic solutions (pH greater than 7): They have a low concentration of hydrogen ions (H +). The higher the pH, the more alkaline or basic the solution. For example, baking soda and bleach are basic and have a pH of around 9-13.

pH value plays an important role in various fields. In the laboratory or research, almost all processes that involve water require pH measurement. This includes chemical diagnostics, environmental science water quality testing, and biological environmental experiments. Therefore, it is important to measure and control pH in different contexts. 


2. pH meter

A pH meter is a specialized scientific instrument that analyzes and measures the acidity or alkalinity of a solution, an important parameter for many applications in different industries, and is an essential tool in many fields that require precise measurements of acidity or alkalinity.

There are many different types of pH meters such as handheld pH meters, desktop pH meters, food pH meters, hydroponic pH meters, pH pens, etc. These types of machines have different features and applications. In this article, we only provide some information about pH meters in solutions.

 
 
 

3. Structure and operating principle
3.1 Structure of pH meter
 

A pH meter is made up of the following main components:

  • Glass sensor electrode: Designed with a bulb made from a special type of glass coated with silica and metal salts. This electrode determines the ability to measure pH through the concentration of hydrogen ions.
  • Reference electrode: Usually a silver–silver chloride electrode, although a mercury–mercury chloride electrode is sometimes used. Its purpose is to provide a stable reference voltage for measurement.
  • Voltmeter: This is attached to both electrodes and measures the voltage difference between them.
  • Voltmeter: This is attached to both electrodes and measures the voltage difference between them.
3.2 Operating principle of pH meter
The basic operating principle of a pH meter is to measure the concentration of hydrogen ions. Acids dissolve in water to form positively charged hydrogen ions (H+). If the Hydrogen ion has a positive charge, its acidity will be greater and vice versa. The difference in potential between these two electrodes is measured and converted to a pH value using a pH meter. The watch then displays this value on its display. 
 

4. Application
A solution pH meter is a commonly used device for measuring and controlling solution quality. Some common applications of pH meters include:

- In the laboratory: In chemistry experiments, pH is important in chemical reactions and often needs to be controlled or adjusted for optimal reactions

- Environmental science: pH is an important parameter in water quality and wastewater treatment. It affects the solubility and toxicity of chemicals and heavy metals in the water supply.

- Food and beverage industry: The food industry uses pH meters to measure acidity in food and beverages. This helps ensure safety and quality, as well as meeting regulatory requirements.


5. Why should you calibrate a pH meter? 
After long periods of operation or aging, the pH meter's stability, accuracy, and performance gradually decrease. At this time, the pH meter needs to be calibrated. Periodic calibration is extremely necessary, playing an important role in:
  • Link measuring instruments to measurement standards to ensure consistency and accuracy of measurement
  • Ensure the reliability of measuring equipment with measurement results
  • Early detection of damage to take timely maintenance, repair, or replacement measures (if necessary), reducing technical, financial, and environmental risks. 

6. Calibration procedure for pH meter
Below is a summary of the pH meter calibration procedure referenced from technical documents ĐLVN 31:2017. The equipment calibration process will have certain differences in the method (internal process) compared to the general standards ĐLVN 31:2017.
6.1 Calibration means 

- The means used for calibration are listed in the following table

6.2 Calibration conditions
When performing calibration, the following environmental conditions must be ensured:

                        + Ambient temperature: (25 ± 5)°C

                        + Environmental humidity: ≤ 80%RH (no dew)

6.3 Prepare for calibration

- Before performing calibration, the following preparations must be performed:

- Select calibration points

- The standard solution is kept temperature stable at (25 ± 0.05) oC using a thermostatic bath.

- Before performing calibration, the probe of the pH measuring device (referred to as UUT) must be cleaned with an appropriate solvent depending on the material used to make the probe, according to the manufacturer's instructions in the documentation. technical materials, then rinse with distilled water. 

6.4 Perform Calibration

6.4.1 Initial Inspection
​- Visually check to determine the UUT's compliance with the requirements specified in the technical documents regarding shape, size, display, power source used, brand, and attached accessories. 
6.4.2 Technical Inspection

Technical inspection must comply with the following requirements:

- Check the normal operating status and adjustment mechanism of the PTB according to technical documents 

6.4.3 Measurement inspection
UUT is checked and measured according to the following content, method, and requirements: 
​- Check the errors
- Check the repeatability
- Check the stability (drift)
6.5 Estimate the measurement Uncertainty
6.6 General handling
After calibration, the pH measuring instrument is stamped and issued a calibration certificate with calibration results.

Recommended calibration cycle: 01 year

 

To consult and request a quote on our pH meter calibration services, please kindly contact us via the following information:

LABORATORY: DONG TAM MEASUREMENT AND TECHNICAL TRADING SERVICE CO., LTD

ADDRESS: No.57-59 Street 11, Binh Hung Residential Area, Binh Hung Commune, Binh Chanh District, Ho Chi Minh City

TEL: 028 375 83 869 - Hotline: 0909 347 891 (Mr. Lâm)

Email: info@dongtam-mes.vn